Looking at the setup of an electrochemical cell, what happens when \(E_{ext}\) > 1.1 V
Limiting molar conductivity of NH4OH is equal to -: a. Λᵒₘ(NH₄Cl) + Λᵒₘ(NaCl) + Λᵒₘ(NaOH) b. Λᵒₘ(NaOH) + Λᵒₘ(NaCl) - Λᵒₘ(NH₄Cl) c. Λᵒₘ(NaOH) - Λᵒₘ(NH₄Cl) - Λᵒₘ(HCl) d. Λᵒₘ(NH₄Cl) + Λᵒₘ(NaOH) - Λᵒₘ(NaCl)
How is electrical conductance of a conductor related with length and area of cross-section of the conductor? a. G = \(l. a.k^{-1}\) b. G = \(k. l.a^{-1}\) c. G = \(k.a. l^{-1}\) d. G = \(k. l.a^{-2}\)
The potential of a hydrogen electrode at pH = 10 is a. 0.591 V b. 0.00 V c. – 0.591 V d. -0.059 V
Which cell will measure standard electrode potential of copper electrode? a. Pt (s) | H₂ (g, 0.1 bar) | H⁺ (aq., 1 M)
The difference between the electrode potentials of two electrodes when no current is drawn through the cell is called ___________. a. Cell potential. b. Electromotive Force. c. Potential difference. d. Cell voltage.
Assertion: \(E_o\) cell should have a positive value for the cell to function. Reason: \(E_{cathode}\) < \(E_{anode}\). (A) Both assertion and reason are true and the reason is the correct explanation of assertion. (B) Both assertion and reason are true and the reason is not the correct explanation of assertion. (C) Assertion is true but the reason is false. (D) Assertion is false but the reason is true.
Assertion : Conductivity of all electrolytes decreases on dilution. Reason : On dilution number of ions per unit volume decreases. (A) Both assertion and reason are true and the reason is the correct explanation of assertion. (B) Both assertion and reason are true and the reason is not the correct explanation of assertion. (C) Assertion is true but the reason is false. (D) Assertion is false but the reason is true.
Assertion : Λᵒ m for weak electrolytes shows a sharp increase when the electrolytic solution is diluted. Reason : For weak electrolytes degree of dissociation increases with dilution of solution. (A) Both assertion and reason are true and the reason is the correct explanation of assertion. (B) Both assertion and reason are true and the reason is not the correct explanation of assertion. (C) Assertion is true but the reason is false. (D) Assertion is false but the reason is true.
The conductivity of metals decreases while that of electrolytes increases with increase in temperature. Why?
The conductivity of an aqueous solution of NaCl in a cell is 92 \(Ω^{−1}\) \(cm^{-1}\) the resistance offered by this cell is 247.8 Ω . Calculate the cell constant.
How many electrons flow when a current of 5 amps is passed through a solution for 193 sec ? Given F = 96500 C. \(N_0\) = 6.002 × \(10^{23}\) \(mol^{-1}\).
There are two possible reactions for cathode in the electrolysis of aqueous \(ZnCl_2\) :\(Zn^{2+}\) (aq) + 2\(e^-\) → Zn(s) \(E^0\) = -0.76 V 2\(H_2\)O (l) + 2\(e^-\) → H2 (g) + 2\(OH^-\) (aq) \(E^0\) = - 0.83 V Which one will take place? Why?
Calculate pH of following half-cell. Pt, \(H_2\) / \(H_2\)\(SO_4\) , if its electrode potential is 0.03V.
(a) Calculate G° for the reaction Zn(s) + \(Cu^{2+}\)(aq) → \(Zn^{2+}\)(aq) + Cu(s) Given: E° for \(Zn^{2+}\)/Zn = -0.76V and E° for \(Cu^{2+}\)/Cu = +0.34 V R = 8.314 \(JK^{–1}\) \(mol^{–1}\), F = 96500 \(mol^{–1}\)
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